Comparison Study of PHBA-intercalated Mg/Al-LDH and PHBA-immobilized Mg/Al-LDH: Characterization and Application for [AuCl4]̄ Removal from Solution

Lutfi Aditya Hasnowo, Sri Juari Santosa, Bambang Rusdiarso

Abstract


Synthesis of p-hydroxybenzoic acid (PHBA)-intercalated Mg/Al-LDH and PHBA-immobilized Mg/Al-LDH have been conducted. PHBA-intercalated Mg/Al-LDH hybrid was synthesized by co-assembly process of Mg/Al-LDH nanosheets and PHBA anions. PHBA-immobilized Mg/Al-LDH was prepared by indirect synthesis, where PHBA anions were attached on surface of the Mg/Al-LDH material. Characterization by X-ray Diffraction showed that the PHBA-intercalated Mg/Al-LDH hybrid has the lattice parameter of a=3.02 Å, lattice parameter of c=46.77 Å and basal spacing d003=15.14 Å, where PHBA has been intercalated in interlayer of the hybrid. The PHBA-immobilized Mg/Al-LDH has lattice parameter of a=3.06 Å, lattice parameter of c=23.70 Å and basal spacing d003=7.90 Å. The analytical result confirmed that PHBA has been attached on surface of the hybrid for PHBA-immobilized Mg/Al-LDH. The optimum 10 mL of [AuCl4]‾ 100 mg L-1 removal condition of both hybrids were reached at pH 3. The optimum interaction time of [AuCl4]‾ and PHBA-intercalated Mg/Al-LDH hybrid was 250 minutes, respectively, while that for [AuCl4]‾ and PHBA-immobilized Mg/Al-LDH was 150 minutes. Removal of [AuCl4]‾ by PHBA-intercalated Mg/Al-LDH hybrid followed pseudo second order kinetic, whereas by PHBA-immobilized Mg/Al-LDH followed pseudo first order kinetic. Characterization using stereo photomicroscope confirmed that [AuCl4]‾ could be reduced  to Au  metal by both hybrids.

Full Text:

Full Text PDF

References


J. M. Oh, S. H. Hwang, and J. H. Choy. “The effect of synthetic conditions on tailoring the size of hydrotalcite particles.” Solid State Ionics, vol. 15, no. 1-4, pp. 285–291. 2002.

F. Cavani, F. Trifiro, and A. Vaccari. “Hydrotalcite-type Anionic Clay: Preparation, Properties and Application.” Catalyst Today, vol. 11, pp. 173-301. 1991.

C.O. Oriakhi, I.V. Farr, and M.M. Lerner. “Incorporation of poly (acrylic acid), poly (vinylsulfonate) and poly (styrenesulfonate) within layered double hydroxides.” J. Mater. Chem., vol. 6, pp. 103. 1996

X. F. Wang, S. Q. Liu, and S. P. Li, “Methotrexatum intercalated layered double hydroxides: Statistical design, mechanism explore and bioassay study.” Materials Science and Engineering C, vol. 49, pp. 330–337. 2015.

P.S. Braterman, Z.P. Xu, and F. Yarberry. “Handbook of Layered Materials,” in: S.M. Auerbach, K.A. Carrado, P.K. Dutta Ed. New York: Marcel Dekker Inc., 2004, pp. 373–474.

S. Chowdhury and P. Das Saha. “Comparative Analysis of Linear and Nonlinear Methods of Estimating The Pseudo-Second-Order Kinetic Parameters for Sorption of Malachite Green Onto Pretreated Rice Husk.” Bioremediation Journal, vol. 15, no. 4, pp. 181–188. 2011.

X. F. Wang, S. Q. Liu, and S. P. Li, “Methotrexatum intercalated layered double hydroxides: Statistical design, mechanism explore and bioassay study.” Materials Science and Engineering C, vol. 49, pp. 330–337. 2015.

J. M. Oh, S. H. Hwang, and J. H. Choy. “The Effect of Synthetic Conditions on Tailoring the Size of Hydrotalcite Particles.” Solid State Ionics, vol. 151, no. 1-4, pp. 285–291. 2002.

G. N. Manju, M. C. Gigi, and T. S. Anirudhan, “Hydrotalcite as adsorbent for the removal of chromium(VI) from aqueous media: Equilibrium studies.” Ind. J. Chem. Technol. Vol. 6, pp. 134–141. 1999

T. S. Anirudhan, and P.S. Suchithra., “Synthesis and characterization of tannin-immobilized hydrotalcite as a potential adsorbent of heavy metal ions in effluent treatments. Applied Clay Science, vol. 42, pp. 214–223. 2008

K. T. Basuki, L. A. Hasnowo, and E. Jamayanti. “Adsorption Of Uranium Simulation Waste Using Bentonite: Titanium Dioxide.” Urania-Jurnal Ilmiah Daur Bahan Bakar Nuklir, vol. 25, no. 1, pp. 1-70, Feb. 2019.

L. A. Hasnowo. “Sintesis dan Karakterisasi Material Hibrida Mg/Al-LDH Terimobilisasi Asam Para Hidroksibenzoat.” Jurnal Forum Nuklir, vol. 11, no. 2, Nov. 2017.

Maghfiroh. “Pengaruh Posisi Gugus Hidroksi Senyawa Turunan Asam Benzoat terhadap Pembentukan Nanopartikel Perak dari AgNO3,” M.A. thesis, Universitas Gadjah Mada, Indonesia, 2015

F. S. Karoonian, M. Etesami, and N. Mohamed. “Electrodepositionof Au on Reticulated Vitreous Carbon from Chloride Media by an Electrogenerative Process.” Int. J. Electrochem. Sci., vol. 7, no. 4, pp. 3059–3071. 2012

X. Pang, M. Sun, X. Ma, and W. Hou. “Synthesis of Layered Double Hydroxide Nanosheets by Coprecipitation Using a T-Type Microchannel Reactor.” J. Solid State Chem., vol. 210, no. 1, pp. 111–115. 2014.

S. J. Mills, A. G. Christy, J. M. Genin, T. Kameda, and F. Colombo. “Nomenclature of the Hydrotalcite Supergroup: Natural Layered Double Hydroxides.” Mineral. Mag., vol. 76, no. 5, pp. 1289–1336. 2012

M.S. Frunza, D. Hritcu, and M. I. Popa. “Intercalation of Salicylic Acid into ZnAl Layered Double Hydroxides by Ion-Exchange and Coprecipitation Method.” J. Optoelectron Adv. M., vol. 11, no. 4, pp. 528-434. 2009.

L. Hickey,J. T. Klopprogge, and R. L. Frost. “The ffect of Various Hydrothermal Treatments on Magnesium-Aluminium Hydrotalcites.” J. Mater. Sci., vol. 35, pp. 4347-4353. 2000.

G. Gunzler and H. I. Gremlich, IR Spectroscopy, Wiley-VCH: Weinheim, 2002.

S.J. Santosa, E.S. Kunarti, Karmanto, and N.A. Ikhsan. “Mg/Al layered double hydroxide anionic clay as a potential material for the remediation of acid mine leachate.” Asian J. Env. Tech., vol. 2, pp. 1-10. 2018.

J.T. Kloprogge, D. Wharton, L. Hickey, and R.L. Frost. “Infrared and raman study of interlayer anions CO32-, NO3-, SO42- and ClO4- in Mg/Al hydrotalcite.” Am. Mint, vol. 87, pp. 623-629. 2002.

D. Wan, H. Liu, R. Liu, J. Qu, S. Li, and J. Zhang. “Adsorption of nitrate and nitrite from aqueous solution onto calcined (Mg/Al) hydrotalcite of different Mg/Al ratio.” Chem. Eng. J., vol. 195-196 pp. 241-247. 2012.

M. J. S. Martin, M. V. Villa, and M. S. Camazano, “Glyphosate-Hydrotalcite Interaction as Influenced by pH.” Clays Clay Miner., vol 47, pp. 777-783. 1999.

M. Wojnicki, E. Rudnik, M. Luty-Błocho, K. Pacławski, and K. Fitzner. “Kinetic studies of gold(III) chloride complex reduction and solid phase precipitation in acidic aqueous system using dimethylamine borane as reducing agent.” Hydrometallurgy, vol. 127, pp. 43–53. 2012.

J. Paclawski and K. Fitzner. “Kinetics of gold(III) chloride complex reduction using sulfur(IV).” Metall. Mater. Trans, vol. 35, pp. 1071-1085, 2004.

K. Pacławsk and T. Sak. “Kinetics and Mechanism of the Reaction of Gold(III) Chloride Complexes with Formic Acid.” J. Min. Metall., Sect. B Metall., vol. 51, no. 2, pp. 133–142. 2015.

H, B. Luo, Hd and Y. Y. Xie. “Regioselective Oxidations of Phenols to o-Quinones with Dess-Martin periodenane (DMP).” Chin. Chem. Lett, vol. 14, no. 6, pp. 555-556. 2003.

F. C. Wu., R. L. Tseng., and R. S. Juang. “Kinetic modeling of liquid-phase adsorption of reactive dyes and metal ions on chitosan.” Water Research, vol. 35, no. 3, pp. 613-618. 2001.

I. A. W. Tan, A. L. Ahmad, and B. H. Hameed. “Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies.” Journal of Hazardous Material, vol. 154, no. 1-3, pp. 337-346. 2008.

K. V. Kumar. “Linear and Non-Linear Regression Analysis for the Sorption Kinetics of Methylene Blue onto Activated Carbon.” J. Hazard. Mater., vol. 137, pp. 1538–1544. 2006.

K. Pacławski, and T. Sak. “Kinetics and Mechanism of the Reaction of Gold(III) Chloride Complexes with Formic Acid.” J. Min. Metall., Sect. B Metall., vol. 51, no. 2, pp. 133–142. 2015

S. Lagergren. “Zur Theorie der sogenannten Adsorption gelöster Stoffe.” Kungliga Svenska Vetenskapsakad. Handlingar, vol. 24, pp. 1–39. 1898.

Y.S. Ho and G. McKay. “The kinetics of sorption of divalent metal ions onto sphagnum moss peat.” Water Res, vol. 34, pp. 735–742. 2000.

S.J. Santosa. “Sorption kinetics of Cd(II) species on humic acid-based sorbent.” Clean–Soil, Air, Water, vol. 42, pp. 760–776. 2014

S. J. Santosa. “Gallic and Salicylic Acid-Functionalized Mg/Al Hydrotalcite as Highly Effective Materials for Reductive Adsorption of AuCl4-.” Applied Surface Science, vol. 507 pp. 145115. 2020

R. Rusdianasari, M. Taufik, Y. Bow, and M. S. Fitria. “Application of Nanosilica from Rice Husk Ash as Iron Metal (Fe) Adsorbent in Textile Wastewater.” Indonesian Journal of Fundamental and Applied Chemistry, vol. 5, no. 1, pp. 7-12. 2020

M. Misriyani, T. Setianingsih, and D. Darjito. “Effect of Carbonization Time of Mesoporous Carbon in the Dyes Adsorption: Rhodamine B, Methylene Blue and Carmine.” Indonesian Journal of Fundamental and Applied Chemistry, vol. 5, no. 1, pp. 1-6. 2020

R. Mohadi, Hermansyah, P. Loekitowati, Z. Hanafiah, and H. Zulkifli. “Kinetic and Thermodynamic Study Removal of Co(II) Using Biosorbent Spirulina sp. in Aqueous Solution.” Indonesian Journal of Fundamental and Applied Chemistry, vol. 2, no. 4, pp. 83-86. 2017

Krisbiantoro, P.A. “Synthesis Magnetit Asam Fulvat (Fe3O4-AF) dan Aplikasinya untuk Adsorpsi-reduksi Ion [AuCl4]‾.” M.A. thesis, Universitas Gadjah Mada, Indonesia, 2016.




DOI: http://dx.doi.org/10.24845/ijfac.v5.i3.78

Refbacks

  • There are currently no refbacks.


 

Editorial Office:

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.35 Indralaya Ogan Ilir Sumatera Selatan 30662

 

 

Creative Commons License
IJFAC by Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License