Biodiesel Production from Waste Cooking Oil
Abstract
Increased energy consumption and the depletion of petroleum reserves have pushed up oil prices globally. The diminishing petroleum reserves are a problem inherent in this type of fossil energy. One alternative energy source that has the potential to be developed in Indonesia is biodiesel. Used cooking oil or used cooking oil is a potential raw material for making biodiesel. In this study biodiesel was made from used cooking oil and methanol using the transesterification method with KOH catalyst. The production of biodiesel from used cooking oil begins with mixing raw materials of used cooking oil collected into one. The mixture is then precipitated for 24 hours. The transesterification process was carried out by mixing KOH (1% of oil weight) with methanol (ratio
of methanol: oil 6: 1) at a temperature of 65 oC. After the temperature is reached, the methanol and KOH solution is added slowly while pumping (stirring), with a variation of time 30, 45, 60.75 and 90 minutes. Biodiesel purification is done by washing using hot water (temperature 70 C) twice as much washing. Characteristics of biodiesel based on the best conditions for density 0.886 g / mL, viscosity 5.89 cSt, FFA 0.11% , acid value 0.256 mgKOH/g and flash point 170.52 oC. The biodiesel products based on these parameters meet SNI 7182-2015 standards.
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BPPT (badan Pengkajian dan Penerapan Teknologi)., Outlook Energy Indonesia., 2014.
A.B. Chhetri, K.W., Islam, M.R., “Waste Cooking Oil as an Alternate Feedstock for Biodiesel Productionâ€, Energies, 1996-1073, 2008.
Direktorat Jendral Perkebunan., Pertumbuhan Kelapa Sawit., www.ditjenbun.pertanian.go.id, 21 November, 2014.
GAPKI (Gabungan Pengusaha Kelapa Sawit Indonesia)., Konsumsi Sawit Indonesia, www.sawitindonesia.com, 29 April, 2015
S. Suroso., “Efektifitas Pemanfaatan Minyak Goreng Bekas (Minyak Jelantah) Menjadi Biosolar Sebagai Bahan Bakar Alternatif Dikota Surakartaâ€, J. Autindo, Vol.1.Nomor 3, 2016
Y. Shimada, Y.Watanabe, A. Sugihara and Y. Tominaga, “Enzymatic Alcoholysis for Biodiesel Fuel Productionand Application of the Reaction
to Oil Processingâ€, J.of Molecular Catalysis B:Enzymatic, Vol.17, No.3-5, pp.360-364,2002.
F.R. Ma and M.A. Hanna “ Biodiesel Production: A Review“, Bioresource Technology, Vol.70, No.1, pp.1-15, 1999
M.P.Dorado, E.Ballesteros, F.J.Lopez and Mittelbach, “ Optimization of Alkali-Catalyzed Transesterification of Brassica Carinate Oil for Biodiesel Productionâ€, Energy Fuels, Vo.18, No.1, pp.77-83,2004
P.D. Patil., V.G. Gude., H.K.Reddy., T. Muppaneni., S.Deng, “ Biodiesel Production from waste Cooking Oil Using Sulfuric Acid and Microwave Irradiation Processesâ€, J. of Environmental Protection, Vol.3. pp.107-
,2012
M.D. Solikhah., Paryanto, I., Barus , B.R., “Efek Kualitas Minyak Jelantah terhadap Harga Proses Produksi dan Kualitas Biodieselâ€, Prosiding Seminar Nasional Teknik Kimia Indonesia-SNTKI, Bandung. 2009.
Y.Wang., Qou., S.,Liu., P., Zhang, Z.,â€Preparation of Biodiesel from Waste Cooking Oil via Two-Step Catalyzed Process, Energy Conversion & Management, Vol.48, Issue 1, pp. 184-188, 2007
Hasanudin, Rachmat, A.,†Production of Biodiesel from Esterification of Oil Recovered from Palm Oil Mill Effluent (POME) Sludge using Tungstated-Zirconia Composite Catalystâ€. Indonesian Journal of Fundamental and Applied Chemistry, Vol. I, No.2, pp. 42-46, 2016
Encinar, Jose. M., “ Preparation and Properties of Biodiesel from Cynara Carduncus L.Oilâ€, Industrial and Engineering Chemistry Research,
Vol. 38.,No.8, pp 2927–2931, 1999
Sanli, H., Canakei, M., Alptekin, E, “Characterization of Waste Frying Oils Obtained from Different Fasilitiesâ€. In Word Renewable Energy Congress, Linkoping,Sweden, 2011
Haryono., C.L.,Natanel, I.,Rahayu, A.N., Wicaksono,†Esterifikasi dan Transesterifikasi Serempak Minyak Jelantah menjadi Biodiesel
dengan Katalis Resin Penukar Kationâ€, Prosiding Seminar Nasional MIPA, 2016.
E. Setiawati., F. Edwar.,†Teknologi Pengolahan Biodiesel dari Minyak Goreng Bekas dengan Teknik Mikrofiltrasi dan Transesterifikasi
sebagai Alternatif Bahan Bakar Mesin Dieselâ€, Jurnal Riset Industri , Vol.6, No. 2, hal. 117-127,2012.
E.S. Yusmartini., Rusdianasari, “Separation Process Biodiesel from Waste Cooking Oil Using Ultrafiltration Membranesâ€,Proceeding First,
S.V., Sinaga.,A. Haryanto.,S. Triyono,â€Pengaruh Suhu dan Waktu Reaksi pada Proses Pembuatan Biodiesel dari Minyak Jelantahâ€, Jurnal Teknik Pertanian, Vol 3, No 1.pp 27-34, 2014
Budiman., R.D., Kusumaningtyas, Y.S., Pradana, N.A., Lestari, “Biodiesel: Bahan Baku, Proses dan Teknologiâ€, cetakan pertama, Gajah Mada, 2014.
Machmud, S., “Pengaruh Perbandingan Solar – Biodiesel (minyak jelantah) terhadap Emisi Gas Buang pada Motor Dieselâ€, Jurnal Janateknika, Vol.11 No.2, 2009.
S. Wahyuni, Ramli, Mahrizal, “Pengaruh Suhu Proses dan Lama Pengendapan terhadap Kualitas Biodiesel dari Minyak Jelantahâ€, Pillar of
Physics, Vol.6, hal.33-40, 2015
R.Prihandana., Hendroko, R. dan M.,Nuramin, M. 2006. Menghasilkan Biodiesel Murah, Mengatasi Polusi dan Kelangkaan BBM.
Agromedia Pustaka, Jakarta, 2006
S. Ketaren, “Pengantar Teknologi Minyak dan Lemak Panganâ€. Universitas Indonesia. Jakarta 2005.
E. Hambali, “Teknologi Bioenergiâ€, Jakarta:Agro Media Pustaka, 2007
S. Sudarmadji., B. Haryono and Suhardi, “Analisa Bahan Makanan dan Pertanianâ€, Edisi Kedua, Liberty, Yogyakarta, pp.93-104,2003
Fitriani, “Produksi Biodiesel dari Minyak Jelantah melalui Transesterifikasi dengan Bantuan Gelombang Ultrasonikâ€, Bandar
Lampung:Lampung, 2016.
DOI: http://dx.doi.org/10.24845/ijfac.v3.i3.77
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