Modification of CaO from Quail Egg Shells with Sodium Dodecyl Sulfate through Extraction and Precipitation Method as Adsorbent for Methylene Blue Dyes

Widia Purwaningrum, Yolanda Fany Claudia Manurung, Fatma Fatma, Ady Mara

Abstract


Calcium oxide (CaO) is widely used as an adsorbent due to high adsorption effectiveness and can adsorb metals in wastewater and dye waste. The aim of this research is to synthesize CaO from quail egg shells and then modify it using sodium dodecyl sulfate surfactant. Synthesis of CaO was carried out through the extraction method using HCl 1% and precipitation method using Na2CO3 1M. Modified CaO was synthesized by the same method with the addition of Sodium Dodecyl Sulfate (SDS).  Diffractogram peaks on CaO and  CaO modifications are similar to JCPDS data No.88-1811. CaO IR spectrum modification after adsorption showed the addition of functional groups C-N and C=N from methylene blue. CaO and CaO's modifications had pHpzc of 11.82 and 11.62. CaO modification using SDS caused a decrease in the surface area of CaO from 3.9 to 2.5 m2/g and an increase in the pore radius from 3.6 to 13.5 nm. Modification of CaO using SDS decrease the surface area of CaO but adsorption capacity increases 66.19% from 44.63 mg/g to 74.17 mg/g. Kinetic model and adsorption isotherm on CaO and CaO modifications occur in pseudo-second order by following the Langmuir isotherm model. The adsorption process is endothermic and adsorption occurs spontaneously with positive ∆Ho and negative ∆Go values at each adsorption temperature


Full Text:

Full text - PDF

References


. W. B. Firmansyah, M. Rokhmat, & E. Wibowo, “Pelapisan Titanium Dioksida Pada Plastik Mika Sebagai Fotokatalis Untuk Mendegradasi Metilen Biru Titanium Dioxide Coating on Mica Plastic as Photocatalist for,” .e-Proceeding of Engineering. Vol. 6, no. 1, pp. 1157–1164, 2019.

. S. Dagher, A. M. Soliman, A. Ziout, N. Tit, A Hilal-Alnaqbi, S. A. Khashan, F. Alnaimat & J. E. A. Qudeiri, “Photocatalytic Removal of Methylene Blue Using Titania- and Silica Coated Magnetic Nanoparticle,” Materials Research Express, vol. 5, pp. 065518, 2018.

. F. W. Sausan, A. R. Puspitasari, D. Y. Purwaningsih. “Studi Literatur Pengolahan Warna pada Limbah Cair Industri Tekstil Menggunakan Metode Proses diantaranya Senyawa Hidrokarbon Aromatik, Fenol beserta Turunannya,” Tecnoscienza, Vol. 5, No. 2, pp. 1-11, 2021.

. R. Mahini, H. Esmaeili & R. Foroutan,” Adsorption of Methyl Violet from Aqueous Solution Using Brown Algae Padina sanctae-crucis,” Turkish Journal of Biochemistry, vol. 43, no. 6, pp. 623–631, 2018.

. S. Khoo & H. Esmaeili., “Synthesis of CaO/Fe3O4 Magnetic Composite for the Removal of Pb(II) and Co(II) from Synthetic Wastewater,” Journal of the Serbian Chemical Society, vol. 82, pp. 1-8, 2018.

. H. Esmaeili, and R. Foroutan, “Investigation into Ion Exchange and Adsorption Methods for Removing Heavy Metals from Aqueous Solutions,” International Journal of Biology, Pharmacy and Allied Sciences, vol. 4, pp. 620–9, 2015.

. U. M. Anggriani, A. Hasan, & I. Purnamasari, “Kinetika Adsorpsi Karbon Aktif Dalam Penurnan Konsentrasi Logam Tembaga (Cu) Dan Timbal (Pb),” Jurnal Kinetika, vol. 12, no. 2, pp. 29–37, 2021.

. N. A. I. Rahayu, N. Sylvia, S. Bahri, Meriatna, A. Muarif, “Adsorpsi Zat Warna Methylene Blue Menggunakan Adsorben dari Ampas Teh Pada Kolom,” Chemical Engineering Journal Storage vol. 2, no. 2, pp. 75-86, 2022.

. S. Jefri & Rodiah, “CaO Adsorbent for Reducing Metal Content of Fe, Mn, and Zn from Pet-Set Waste-Water,” Jambura Journal of Health Science and Research, vol. 4, no. 3, pp. 1-9, 2022.

. S. Thakur, S. Singh, & B. Pal,” Superior Adsorption Removal of Dye and High Catalytic Activity for Transesterification Reaction Displayed by Crystalline CaO Nanocubes Extracted from Mollusc Shells,” Fuel Processing Technology, vol. 213, pp. 106707, 2021.

. N. Widiarti, dan E. F. Rahayu, “Sintesis CaO.SrO dan Aplikasinya Pada Reaksi Transesterifikasi Minyak Jelantah Menjadi Biodiesel,” Indonesian Journal of Chemical Science, vol. 5, no.1, pp. 19-27, 2016.

. W. Purwaningrum, Hasanudin, A. Rachmat, F. Riyanti, P. L. Hariani, “Modification of Calcium Oxide from Green Mussel Shell with Iron Oxide as a Potential Adsorbent for the Removal of Iron and Manganese Ions from Acid Mine Drainage,” Journal of Ecological Engineering, vol. 23, no. 11, pp. 188 –201, 2022.

. W. Purwaningrum, Hasanudin, A. Rachmat, F. Riyanti, P. L. Hariani, “Magnetic Composite for Efficient Adsorption of Iron and Manganese Ions from Aqueous Solution,” Ecological Engineering & Environmental Technology, vol. 24, no. 8, pp. 143–154, 2023.

. D. Yonata, S. Aminah, & W. Hersoelistyorini, “Kadar Kalsium dan Karakteristik Fisik Tepung Cangkang Telur Unggas dengan Perendaman Berbagai Pelarut,” Jurnal Pangan Dan Gizi, vol. 7, no. 2, pp. 82–93, 2017.

. E. Budi, & S. Iwan, “Pengaruh Variasi Konsentrasi Sodium Dodecyl Sulfate (C12H25NaSO4) Terhadap Morfologi Permukaan Pada Pembentukan Lapisan Tipis Komposit Ni-TiAlN Dengan Metode Elektrodeposisi”, in Prosiding Seminar Nasional Fisika (E-Journal) 2017, pp 1-4.

. P. Jamrunroj, S. Wongsakulphasatch, A. Maneedaeng, C KuiCheng, & S. Assabumrungrat, “Surfactant Assisted CaO-Based Sorbent Synthesis and their Application to High-Temperature CO2 Capture,” Powder Technology, vol. 344, pp. 208–221, 2019.

. S. L. Hsieh, F. Y. Li, P. Y. Lin, D. E. Beck, R. Kirankumar, G. J. Wang, & S. Hsieh, “CaO Recovered from Eggshell Waste as a Potential Adsorbent for Greenhouse Gas CO2,” Journal of Environmental Management, vol. 297, pp. 113430, 2021.

. R. Zein, N. Wardana., Refillda., dan H. Aziz, “Kulit Salak sebagai Biosorben Potensial untuk Pengolahan Timbal (II) dan Cadmium (II) dalam Larutan,” Chimica et Natura Acta. Vol. 6, no. 2, pp. 56–64, 2018.

. Z. A. ALOthman, M. A. Habila, N. H. Al-Shalan, S. M. Alfadul, R. Ali, I. G. Al Rashed, B Alfarhan, “Adsorptive Removal of Cu (II) and Pb (II) onto Mixed-Waste Activated Carbon: Kinetic, Thermodynamic, and Competitive Studies and Application to Real Wastewater Samples,” Arabian Journal of Geosciences, vol. 9, pp. 315, 2016.

. S. Chatterjee, N. Guha, S. Krishnan, A. K. Singh, P. Mathur, D. K. Rai, “Selective and Recyclable Congo Red Dye Adsorption by Spherical Fe3O4 Nanoparticles Functionalized with 1,2,4,5-Benzenetetracarboxylic Acid,” Scientific Reports, vol. 10, pp. 111, 2020.

. M. N. Sepehr, T. J. Al-Musawi, E. Ghahramani, H. Kazemian, M Zarrabi, “Adsorption Performance of Magnesium/Aluminum Layered Double Hydroxide Nanoparticles for Metronidazole from Aqueous Solution,” Arabian Journal of Chemistry, vol. 10, pp. 611623, 2016.

. B. S. Zadeh, H Esmaeili, R Foroutan, “Cadmium (II) Removal from Aqueous Solution Using Microporous Eggshell: Kinetic and Equilibrium Studies,” Indonesian Journal of Chemistry, Vol. 18, No. 2, pp. 265-271, 2018.

. J. Sibarani, M Zulfihardini, dan I. W. Suarsa, “Sintesis dan Karakterisasi Katalis Cao-Bentonit Untuk Reaksi Transesterifikasi Minyak Jelantah Menjadi Biodiesel,” Cakra Kimia, Indonesian E-Journal of Applied Chemistry, vol. 8, no. 1, pp. 59–65, 2020.

. S. Tamjidi and H. Esmaeili, “Chemically Modified CaO/Fe3O4 Nanocomposite by Sodium Dodecyl Sulfate for Cr (III) Removal from Water,” Chemical Engineering Technology, vol. 42, No. 3, pp. 607–616, 2019.

. Zian, I. Ulfin, dan Harmami, “Pengaruh Waktu Kontak pada Adsorpsi Remazol Violet 5R Menggunakan Adsorben Nata de Coco,” Jurnal Sains dan Seni ITS, Vol. 5 No. 2, pp. 2337-3520, 2016.

. I. Riwayati, N. Fikriyyah, & S. Suwardiyono, “Adsorpsi Zat Warna Methylene Blue Menggunakan Abu Alang-alang (Imperata cylindrica) Teraktivasi Asam Sulfat,” Jurnal Inovasi Teknik Kimia, vol. 4, no. 2, pp. 6–11, 2019.

. S. Z. Aisyahlika, M. L. Firdaus, R. Elvia, “Kapasitas Adsorpsi Arang Aktif Cangkang Bintaro (Cerbera odollam) Terhadap Zat Warna Sintetis Reactive Red-120 dan Reactive Blue-198,” Jurnal Pendidikan Dan Ilmu Kimia. Vol. 2, no. 2, pp. 148-155, 2018.

. A. B. Baunsele, & H. Missa, “Kajian Kinetika Adsorpsi Metilen Biru Menggunakan Adsorben Sabut Kelapa,” Akta Kimia Indonesia, vol. 5, no. 2, pp. 76-85, 2020.

. R. Ragadhita, and A. B. D. Nandiyanto, “How to Calculate Adsorption Isotherms of Particles Using Two-Parameter Monolayer Adsorption Models and Equations,” Indonesian Journal of Science & Technology, vol. 6, no. 1, pp. 205-234, 2021




DOI: http://dx.doi.org/10.24845/ijfac.v9.i3.155

Refbacks

  • There are currently no refbacks.


 

Editorial Office:

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.35 Indralaya Ogan Ilir Sumatera Selatan 30662

 

 

Creative Commons License
IJFAC by Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License