Optimization of Coal Fly Ash Heating Temperature as an Adsorbent to Improve Acid Mine Water Quality
Abstract
Fly ash, a fine dust from coal combustion in steam power plants, is an unused waste material that can be repurposed as a low-cost adsorbent. One type of adsorbent that can be synthesized from fly ash is zeolite-like material (ZLM), which has a porous structure capable of absorbing molecules smaller than or equal to its cavity size. In this study, untreated and heat-activated fly ash at 100, 200, and 300°C was used as an adsorbent for acid mine water. Adsorbent mass varied between 6, 8, 10, 12, and 14 g, mixed with 130 mL of mine water and stirred at 150 rpm for 60 minutes. The results showed that heat activation increased the surface area of the fly ash adsorbent, reaching 22.658 m²/g at 300°C. Heat-treated fly ash at 200 and 300°C showed a more significant reduction in Fe and Mn levels, especially with 8 g of adsorbent. Additionally, all adsorbents, whether heated or not, raised the pH of the acid mine water. The total suspended solids (TSS) were reduced to meet quality standards using 14 g of adsorbent heated to 300°C. These results indicate that coal fly ash adsorbent can be effectively applied for treating acid mine water
Full Text:
Full text - PDFReferences
C. Nugraha and Rolliyah, Pemanfaatan Fly Ash dan Bottom Ash untuk Pengelolaan Batuan dan Air Asam di Tambang Batubara, Direktorat Penilaian Kinerja Pengelolaan Limbah B3 dan Limbah Non B3 Kementerian Lingkungan Hidup dan Kehutanan, Jakarta, Indonesia, 2021.
C. Rodwihok., M. Suwannakaew, S. W. Han, Y. J. Lim, S. Y. Park, S. W. Woo, J. W. Choe, D. Wongratanaphisan, and H. S. Kim, “Effective Removal of Hazardous Organic Contaminant using Integrated Photocatalytic Adsorbents: Ternary Zinc Oxide/Zeolite-Coal Fly Ash/Reduced Graphene Oxide Nanocomposites,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 662, pp. 131044, 2023. doi: 10.1016/j.colsurfa.2023.131044.
E. B. Leksono and A. Abidin, “Pemanfaatan Limbah Fly Ash Batubara sebagai Koagulan dengan Konsep Reverse Logistics,” Jurnal INTECH Teknik Industri Universitas Serang Raya, vol. 7, no. 1, pp. 39-44, 2021. doi: 10.30656/intech.v7i1.2736.
C. Li., C. Zhou, Y. Quan, S. Xu, Z. Wang, Z, Li, X. Lin, G. Liu, and J. Wang, “Synthesis of Hexagonal Mesoporous Silica from Coal Fly Ash and Their Evaluation as Adsorbent for Gallium Recovery,” Journal of Molecular Liquids, vol. 410, pp. 125597, 2024. doi: 10.1016/j.molliq.2024.125597.
R. Nsiah-Gyambibi, Y. A. Sokama-Neuyam, P. Boakye, W. Ampomah, W. Aggrey, and S. Wang, “Valorization of Coal Fly Ash (CFA): A Multi-Industry Review,” International Journal of Environmental Science and Technology, vol. 20, no. 11, pp. 12807-12822, 2023. doi: 10.1007/s13762-023-04895-9.
D. Valeev and A. Kondratiev, “Current State of Coal Fly Ash Utilization: Characterization and Application,” Materials, vol. 16, no. 1, pp. 27-33, 2023. doi: 10.3390/ma16010027.
B. S. Thomas, P. Dimitriadis, C. Kundu, S. S. V. Vuppaladadiyam, R. K. S. Raman, and S. Bhattacharya, “Extraction and Separation of Rare Earth Elements from Coal and Coal Fly Ash: A Review on Fundamental Understanding and On-going Engineering Advancements,” Journal of Environmental Chemical Engineering, vol. 12, no. 3, pp. 112769, 2024. doi: 10.1016/j.jece.2024.112769.
S. U. Hasanah, “Potensi Pemanfaatan Abu Layang untuk Mereduksi Logam Berat di Air Asam Tambang dengan Metode Koagulasi dan Aktivasi Asam Klorida,” S.T. thesis, Universitas Indonesia, Jawa Barat, Indonesia, Feb. 2020.
T. Jiang, J. Hu, S. Wu, D. Shen, and P. Lu, “A Shape-Stable Phase Change Material for High-Temperature Thermal Energy Storage Based on Coal Fly Ash and Na2SO4-K2SO4,” Solar Energy, vol. 280, pp. 112868, 2024. doi: 10.1016/j.solener.2024.112868.
X. Jia, Y. Liu, Z. Yang, A. Zhang, P. Liu, and Z. Liu, “Construction of Coal Fly Ash-Based Spherical Grain Adsorbents and Their Adsorption Characteristics on Phenolic Compounds,” Colloids and Surfaces C: Environmental Aspects, vol. 2, pp. 100042, 2024. doi: 10.1016/j.colsuc.2024.100042.
N. Arofah, A. N. Izzati, Y. D. I. Siregar, Y. N. Azizah, and A. R. Liandi, “Utilization of Magnetite-Supported Coal Fly Ash as An Efficient Adsorbent for Pb Metal Removal in Aqueous Environments,” Case Studies in Chemical and Environmental Engineering, vol. 10, pp. 100883, 2024. doi: 10.1016/j.cscee.2024.100883.
Y. Wang, B. Chen, T. Xiong, Y. Zhang, and W. Zhu, “Immobilization of U(VI) in Wastewater using Coal Fly Ash Aerogel (CFAA) as A Low-Cost Adsorbent,” Process Safety and Environmental Protection, vol. 160, pp. 900–909, 2022. doi: 10.1016/j.psep.2022.03.006.
N. A. Rahman, E. P. Pardede, and A. Mularen, “Pemurnian Minyak Jelantah Menggunakan Adsorben Berbasis Cangkang Telur,” Prosiding SENIATI, vol. 6, no. 4, p. 785-793, 2022, doi: 10.36040/seniati.v6i4.5048.
M. A. Muttaqii, D. C. Birawidha, M. Amin, K. Isnugroho, Y. Hendronursito, E. Prasetyo. A. S. Handoko, L. Marlinda, and Y. Wulandari, “Zeolite Alam Lampung Berpenyangga Logam TiO2 dan ZnO sebagai Nano-Katalis untuk Memproduksi Biodiesel,” Research Report, Balai Penelitian Teknologi Mineral – Lembaga Ilmu Pengetahuan Indonesia, Lampung, Indonesia, Dec. 2020.
S. Yefremova, A. Kablanbekov, B. Satbaev, and A. Zharmenov, “Rice Husk-Based Adsorbents for Removal of Metals from Aqueous Solutions,” Materials, vol. 16, No. 23, pp. 7353, 2023. doi: 10.3390/ma16237353.
A. P. Gobel, E. Nursanto, and W.D. Ratminah, “Efektifitas Pemanfaatan Fly Ash Batubara sebagai Adsorben dalam Menetralisir Air Asam Tambang pada Settling Pond Penambangan Banko PT. Bukit Asam (Persero) Tbk.” Jurnal Mineral Energi dan Lingkungan, vol 2. no. 1, pp. 1-11, 2018. doi: 10.31315/jmel.v2i1.2113.
M. Arifin., M. S. Said, F. N. Yusuf, Harwan, C. A. Chalik, S. R. Nurhawaisyah, N. Jafar, N. Asmiani, A. F. Heriansyah, Ansariah, and A. A. Budiman, “Analisis Karakteristik Penetralan Fly Ash Batubara terhadap Air Asam dengan Metode Acid Buffer Characteristic Curve,” Jurnal Geomine, vol. 9, no. 3, pp 218-288, 2021. doi: 10.33536/jg.v9i3.980.
L D. K. Wardani, “Karakteristik Fly Ash (Abu Layang) Sebagai Material Adsorben pada Limbah Cair yang Mengandung logam,” S.T. thesis, Universitas Negeri Yogyakarta, Daerah Istimewa Yogyakarta, Indonesia, July 2018.
S. E. Putri and S. Side, “Analisis Kandungan Oksida Logam Zeolit Alam Sulawesi Selatan Teraktivasi Asam Klorida,” Jurnal Sainsmat, vol. 9, no. 2, pp. 159-163, 2020, doi: 10.35580/sainsmat92153842020.
A. Ramadhani and S. Khuzaimah, “Pemanfaatan Limbah FABA (Fly Ash Bottom Ash) PLTU Karangkandri sebagai Adsorben Pengolahan Limbah Batik di Desa Kutawaru Cilacap,” Rekayasa Bahan Alam dan Energi Berkelanjutan, vol. 7, no. 2, pp. 25–32, 2023. doi: 10.21776/ub.rbaet.2023.007.02.04.
M. Roulia, D. Alexopoulos, G. Itskos, and C. Vasilatos, “Lignite Fly Ash Utilization for Acid Mine Drainage Neutralization and Clean-up,” Cleaner Materials, vol. 6, pp. 100142, 2022. doi: 10.1016/j.clema.2022.100142.
S. Aima, I. Zahrina, and Zultiniar, “Adsorpsi Logam Fe dengan Zeolit 4A yang Disintesis dari Fly Ash Sawit,” S.T. thesis, Universitas Riau, Riau, Indonesia, Oct. 2012.
H. Pratama, E. Nursanto, and R. Ernawati, “Efektivitas Kenaikan pH dan Penurunan Konsentrasi Logam Berat pada Air Asam Tambang Menggunakan Fly Ash Sisa Pembakaran Batubara PLTU,” Jurnal Ilmiah Lingkungan Kebumian, vol. 4, no. 1, pp. 27–33, 2021. doi: 10.31315/jilk.v3i2.4302.
DOI: http://dx.doi.org/10.24845/ijfac.v9.i3.139
Refbacks
- There are currently no refbacks.
Editorial Office:
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.35 Indralaya Ogan Ilir Sumatera Selatan 30662
IJFAC by Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License