Synthesis and Characterization of ZnO with Calcination Temperature Variation and Surfactant Addition using Chemical Coprecipitation Method

Charlena Charlena, Sri Sugiarti, Yemima Chellyne Khefanny

Abstract


This study aims to synthesize ZnO using the coprecipitation method and characterize it using various instrumentation techniques. The calcination temperature variation treatment was carried out to produce particles with good size and crystallinity levels. Adding polyvinyl pyrrolidone (PVP) surfactant during the synthesis of ZnO aims to prevent agglomeration. ZnO characterization used ultraviolet-visible spectroscopy (UV-Vis), X-ray diffraction (XRD), Fourier transform spectroscopy (FTIR), and scanning electron microscopy (SEM). The result showed that the value of the ZnO band gap increased with increasing temperature. ZnO synthesized at a calcination temperature of 800 °C has a hexagonal wurtzite structure. The crystal size of ZnO is 45.64 nm, while ZnO-PVP's is 40.37 nm. The best ZnO crystallinity level is 61.34%. The FTIR spectrum shows ZnO absorption in the fingerprint region (525 cm-1). SEM micrographs showed that ZnO without the addition of PVP agglomerated. The synthesized ZnO has an antibacterial activity, indicated by forming an inhibition zone (7.84 mm

Full Text:

Full-text PDF

References


. Z. Fan, & J. G. Lu, “Zinc oxide nanostructures: synthesis and properties”, Journal of Nanoscience and Nanotechnology, vol. 5, no. 10, pp. 1561–1573, 2005.

. A. T. Surono, & H. Sutanto, “Sifat optik zinc oxide (ZnO) yang dideposisi di atas substrat kaca menggunakan metode chemical solution deposition (CSD) dan aplikasinya untuk degradasi zat warna methylene blue”, Youngster Physics Journal, vol. 2, no. 1, pp. 7–14, 2014.

. I. Sabarisman, N. E. Suyatma, U. Ahmad, F. M. Taqi, “Aplikasi nanocoating berbasis pektin dan nanopartikel ZnO untuk mempertahankan kesegaran salak pondoh”, Jurnal Mutu Pangan., vol. 2, no. 1, pp. 50–56, 2015.

. T. C. Raganata, H. Aritonang, & E. Suryanto, “Sintesis fotokatalis nanopartikel ZnO untuk mendegradasi zat warna methylene blue,” Chemistry Progress, vol. 12, no. 2, pp. 54–58, 2019.

. A. Sirelkhatim, S. Mahmud, A. Seeni, N. H. M. Kaus, L. C. Ann, S. K. M. Bakhori, H. Hasan, D. Mohamad, “Review on zinc oxide nanoparticles: antibacterial activity and toxicity mechanism”, Nano-Micro Letters., vol. 7, no. 3, pp. 219–242, 2015.

. E. Novarini, & T. Wahyudi, “Sintesis nanopartikel seng oksida (ZnO) menggunakan surfaktan sebagai stabilisator dan aplikasinya pada pembuatan tekstil anti bakteri”, Arena Tekstil., vol. 26, no. 2, pp. 81–87, 2011.

. T. Y. Rozi, & Astuti, “Pengaruh temperatur kalsinasi pada sintesis nanopartikel silika pantai purus kota Padang”, Jurnal Fisika Unand, vol. 5, no. 4, pp. 351–356, 2016.

. Muflihatun, S. Shofiah, & E. Suharyadi, “Sintesis nanopartikel nickel ferrite (NiFe2O4) dengan metode kopresipitasi dan karakterisasi sifat kemagnetannya”, Jurnal Fisika Unand, vol. 19, no. 55, pp. 20–25, 2015.

. Z. Nisa, & Munasir, “Studi morfologi silika hasil kalsinasi dengan metode sintesis hidrotermal-kopresipitasi”, Inovasi Fisika Indonesia, vol. 4, no. 1, pp. 41–44, 2015.

. M. Indriati, R. Nuryanto, & L. Suyati, “Effect of calcination temperature on conductivity and crystallinity of NaMn2-xMgxO4 solid electrolyte”, Jurnal Kimia Sains dan Aplikasi, vol. 16, no. 2, pp.46–49, 2013.

. Yunita, N. Nurlina, & I. Syahbanu, “Sintesis nanopartikel zink oksida (ZnO) dengan penambahan ekstrak klorofil sebagai capping agent”, Positron, vol. 10, no. 2, pp. 123–130, 2020.

. M. G. Kotresh, M. K. Patil, & S. R. Inamdar, “Reaction temperature based synthesis of ZnO nanoparticles using co-precipitation method: detailed structural and optical characterization”, Optik (Stuttg)., vol. 243, pp. 167506, 2021.

. A. D. Rosanti, A. R. K. Wardani, & H. A. Anggraeni, “Pengaruh suhu kalsinasi terhadap karakteristik dan aktivitas fotokatalis N/TiO2 pada penjernihan limbah batik tenun ikat Kediri”, Cakra Kimia, vol. 8, no. 1, pp. 26–33, 2020.

. Z. J. Yu, M. R. Kumar, D. L. Sun, L. T. Wang, & R. Y. Hong, “Large-scale production of hexagonal ZnO nanoparticles using PVP as a surfactant”, Materials Letters, Vol. 166, pp. 284–287, 2016.

. T. Thirugnanam, “Effect of polymers (PEG and PVP) on sol-gel synthesis of microsized zinc oxide”, Journal of Nanomaterials, pp. 1–6, 2013.

. Neldawati, Ratnawulan, & Gusnedi, “Analisis nilai absorbansi dalam penentuan kadar flavonoid untuk berbagai jenis daun tanaman obat:, Pillar of Physics, vol. 2, pp. 76–83, 2013.

. H. Singh, & J. K. Rajput, “Effect of calcination temperature on magnetic, structural, thermal and optical properties of BFO‑T nanoparticles”, SN Applied Sciences, vol. 2, no. 8, pp. 1–11, 2020.

. N. H. Efendi, & H. Sutanto, “The effect of sintering temperature on the optical properties of zinc oxide (ZnO) thin films deposited on glass substrates and their application to degrade methylene blue dye”, Youngster Physics Journal, vol. 3, no. 2, pp. 135–142, 2014.

. E. Gungor, & T. Gungor, “Influence of aluminum concentration on the electrical and optical properties of ZnO thin films”, Journal of the Turkish Chemical Society Section A: Chemistry, Vol. 3, no. 3, pp. 453–462, 2016.

. N. M. Y. Missa, R. K. Pingak, & H. I. Sutaji, “Penentuan celah energi optik ekstrak daun alpukat (Persea americana Mill.) asal desa Oinlasi menggunakan metode tauc plot”, Jurnal Fisika : Fisika Sains dan Aplikasinya, vol. 3, no. 2, pp. 86–90, 2018

. R. Nurbayasari, N. Saridewi, & Shofwatunnisa, “Biosintesis dan karakterisasi nanopartikel ZnO dengan ekstrak rumput laut hijau”, Caulerpa sp. Jurnal Perikanan Universitas Gadjah Mada, Vol. 19, no. 1, pp. 17–28, 2017

. N. Jayarambabu, K. V. Rao, & Y. T. Prabhu, “Beneficial role of zinc oxide nanoparticles on green crop beneficial role of zinc oxide nanoparticles on green crop production”, International Journal of Multidisciplinary Trends, Vol. 2, no. 1, pp. 273–282, 2015.

. P. P. Mahamuni, P. M. Patil, M. J. Dhanavade, M. V. Badiger, P. G. Shadija, A. C. Lokhande, & R. A. Bohara, “Synthesis and characterization of zinc oxide nanoparticles by using polyol chemistry for their antimicrobial and antibiofilm activity”, Biochemistry and Biophysics Reports, Vol. 17, pp. 71–80, 2019.

. J. Chauhan, N. Shrivastav, A. Dugaya, & D. Pandey, “Synthesis and characterization of Ni and Cu doped ZnO”, MOJ Polymer Science, vol. 1, no. 1, pp. 26–34, 2017.

. Masruroh, A. B. Manggara, T. Papilaka, T. R. Triandi, “Penentuan ukuran kristal (crystallite size) lapisan tipis PZT dengan metode XRD melalui pendekatan persamaan Debye Scherrer”, Erudio Journal of Educational Innovation, Vol. 1, no. 2, pp. 24–29, 2013.

. A. E. Suliman, Y. Tang, Z. Xin, & Z. Jia, “The effect of PVP addition and heat-treatment duration on zinc oxide nanoparticles”, Journal of Applied Sciences, Vol. 6, no. 6, pp-1298–1301, 2006.

. R. N. Sari, Nurhasni, & M.A. Yaqin, “Sintesis nanopartikel ZnO ekstrak Sargassum sp. dan karakteristik produknya”, Jurnal Pengolahan Hasil Perikanan Indonesia, Vol. 20, no. 2, pp. 238–254, 2017.

. A. Kareem & M. A. Maamori, “Preparation and characterization of antimicrobial PVA/ZnO nanocomposite for biomaterial applications”, Journal of University of Babylon for Engineering Sciences, vol. 26, no. 2, pp. 286–294, 2018.

. Y. Lestari, P. Ardiningsih, & Nurlina, “Gram-positive and negative antibacterial activity of extracts and fractions of Nipah leaves (Nypa fruticans Wurmb.) from the coast of the Kakap River, West Kalimantan”, Jurnal Kedokteran dan Kesehatan, vol. 5, no. 4, pp. 1–8, 2016




DOI: http://dx.doi.org/10.24845/ijfac.v9.i3.123

Refbacks

  • There are currently no refbacks.


 

Editorial Office:

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.35 Indralaya Ogan Ilir Sumatera Selatan 30662

 

 

Creative Commons License
IJFAC by Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License