Comparison of Acidity Test Method of Nickel Phosphate Silica Catalyst for Production Levulinic Acid from Glucose

Qodria Utami Putri, Hasanudin Hasanudin, Ady Mara

Abstract


The reaction of levulinic acid production from glucose has a reaction stage that requires a high temperature and high activation energy so that in this levulinic acid production reaction a catalyst is needed. The required catalyst must have a lewis acid site and a bronsted acid site so that the acidity of the catalyst is very influential for the successful production of levulonic acid. Silica nickel phosphate catalysts have lewis acid sites from Ni metal and bronsted acid sites from phosphoric and silica groups. The acidity of the catalyst was measured using the pyridine and ammonia adsorption method and the acidity center strength method using the TGA-DTA base adsorption-desorption. The adsorption of ammonia and pyridine uses the gravimetric method so that it can easily obtain the amount of total acidity of the catalyst and the acidity of the catalyst surface while the TGA-DTA method shows the acid strength of the actual catalyst, which is the real state of the catalyst when catalyzing a reaction and shows the catalyst's resistance to high temperatures. These two methods of measuring acidity have the same disadvantage that they cannot show and know the number of lewis acid sites and bronsted acid sites.

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References


Murwinda, R., Sikumbang, S., and Linggawati, A. “Pengaruh Suhu Terhadap Produksi Asam Levulinat.” Jurnal Photon, Vol. 7, No. 1, 2016, pp. 127–135.

Badgujar, K. C., Badgujar, V. C., and Bhanage, B. M. “A Review on Catalytic Synthesis of Energy Rich Fuel Additive Levulinate Compounds from Biomass Derived Levulinic Acid.” Fuel Processing Technology, Vol. 197, No. May 2019, 2020, p. 106213. https://doi.org/10.1016/j.fuproc.2019.106213.

Ranoux, A., Djanashvili, K., Arends, I. W. C. E., and Hanefeld, U. “5-Hydroxymethylfurfural Synthesis From Hexoses Is Autocatalytic.” ACS Catalysis, Vol. 3, No. 4, 2013, pp. 760–763. https://doi.org/10.1021/cs400099a.

Weingarten, R., Kim, Y. T., Tompsett, G. A., Fernández, A., Han, K. S., Hagaman, E. W., Conner, W. C., Dumesic, J. A., and Huber, G. W. “Conversion of Glucose into Levulinic Acid with Solid Metal(IV) Phosphate Catalysts.” Journal of Catalysis, Vol. 304, 2013, pp. 123–134. https://doi.org/10.1016/j.jcat.2013.03.023.

Qu, H., Liu, B., Gao, G., Ma, Y., Zhou, Y., Zhou, H., Li, L., Li, Y., and Liu, S. “Metal-Organic Framework Containing BrØnsted Acidity and Lewis Acidity for Efficient Conversion Glucose to Levulinic Acid.” Fuel Processing Technology, Vol. 193, No. May, 2019, pp. 1–6. https://doi.org/10.1016/j.fuproc.2019.04.035.

Chen, X., Zhang, Y., Hou, T., Han, L., and Xiao, W. “Catalysis Performance Comparison of a BrØnsted Acid H2SO4 and a Lewis Acid Al2(SO4)3 in Methyl Levulinate Production from Biomass Carbohydrates.” Journal of Energy Chemistry, Vol. 27, No. 2, 2018, pp. 552–558. https://doi.org/10.1016/j.jechem.2017.11.005.

Zaccheria, F., Santoro, F., Iftitah, E. D., and Ravasio, N. “Brønsted and Lewis Solid Acid Catalysts in the Valorization of Citronellal.” Catalysts, Vol. 8, No. 10, 2018. https://doi.org/10.3390/catal8100410.

Alemdaroglu, T. “Determination Methods For The Acidity Of Solid Surfaces.” Community Faculty Science, Vol. 47, 2001, pp. 27–35.

Blanco, P. H., Wu, C., Onwudili, J. A., and Williams, P. T. “Characterization and Evaluation of Ni/SiO2 Catalysts for Hydrogen Production and Tar Reduction From Catalytic Steam Pyrolysis-Reforming of Refuse Derived Fuel.” Applied Catalysis B: Environmental, Vols. 134–135, No. 0, 2013, pp. 238–250. https://doi.org/10.1016/j.apcatb.2013.01.016.

Mara, A., Wijaya, K., and Mudasir, W. T. “Effect of Sulfuric Acid Treatment and Calcination on Natural Zeolites of Indonesia.” Asian Journal of Chemistry, Vol. 28, No. 1, 2016, pp. 11–14. https://doi.org/10.14233/ajchem.2016.19107.

Sarifudin, K., Lado, D. Y., Utami, F. S., and Parera, L. A. M. “Sintesis Dan Karakterisasi Sifat Keasaman , Morfologi , Luas Permukaan Spesifik , Rerata Jejari Pori Dan Volume Tatal Pori Katalis K-CoMo / ZAA.” Prosiding Webinar Nasional Pendidikan dan Sains kimia 3 Tahun 2020, Vol. i, 2020, pp. 72–81.

Nugrahaningtyas, K. D., Hidayat, Y., and Prayekti, P. S. “KTIVITAS DAN SELEKTIVITAS KATALIS Mo-Co/USY PADA REAKSI HIDRODEOKSIGENASI ANISOL (ACTIVITY AND SELECTIVITY OF Mo-Co/USY CATALYST ON THE HYDRODEOXYGENATION (HDO) REACTION OF ANISOLE).” Journal of Chemical Information and Modeling, Vol. 53, No. 9, 2013, pp. 1689–1699.

Forni, L. “Catalysis Reviews : Science and Engineering Comparison of the Methods for the Determination of Surface Acidity of Solid Catalysts.” Catal Rev, Vol. 8, No. December 2012, 1974, p. 65.

Liu, D., Yuan, P., Liu, H., Cai, J., Tan, D., He, H., Zhu, J., and Chen, T. “Quantitative Characterization of the Solid Acidity of Montmorillonite Using Combined FTIR and TPD Based on the NH3 Adsorption System.” Applied Clay Science, Vols. 80–81, 2013, pp. 407–412. https://doi.org/10.1016/j.clay.2013.07.006.

Huang, F., Wang, R., Yang, C., Driss, H., Chu, W., and Zhang, H. “Catalytic Performances of Ni/Mesoporous SiO2 Catalysts for Dry Reforming of Methane to Hydrogen.” Journal of Energy Chemistry, Vol. 25, No. 4, 2016, pp. 709–719. https://doi.org/10.1016/j.jechem.2016.03.004.

Gervasini, A., Carniti, P., and Auroux, A. “Surface Acidity of Catalytic Solids Studied by Base Desorption: Experimental and Modelling Approaches.” Thermochimica Acta, Vol. 434, Nos. 1–2, 2005, pp. 42–49. https://doi.org/10.1016/j.tca.2004.12.019.

Kar, K. K., and Sathiyamoorthy, D. “Influence of Process Parameters for Coating of Nickel-Phosphorous on Carbon Fibers.” Journal of Materials Processing Technology, Vol. 209, No. 6, 2009, pp. 3022–3029. https://doi.org/10.1016/j.jmatprotec.2008.07.006.




DOI: http://dx.doi.org/10.24845/ijfac.v7.i3.106

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