The Characteristic of Coal Oil From Catalytic Coal Gasification
Abstract
In this work, the catalytic gasification process of coal was studied at different operating temperatures and catalyst weights. The purpose of this study was to study the characteristics of coal oil produced through the gasification process using Nickel Molybdenum (NiMo) catalyst. The effect of adding NiMo catalyst with variations in weight of 0%, 5%, 10% and 15% for different gasification temperatures (375 – 385 °C, 430 – 440 °C, and 475 – 485 °C) were studied on coal with a calorific value of 6,400 kcal/kg. The process was done in fluidized bed reactor under atmospheric pressure and an air flow rate of 2 liters/minute was flow for 60 minutes. The results showed that NiMo is effective as a catalyst in the gasification of coal at 430 – 440 °C, the addition of 15% weight of catalysts produced coal oil with a yield of 9.35% and the composition of hydrocarbon consists of 59.75% of aromatics, 26.42% of aliphatics, and 7.34% of phenolics. Compared to coal oil without catalyst give a yield of 6.56% with 57.33% of aromatics, 17.44% of aliphatics, and 16.03% of phenolics. This showing that NiMo catalysts have a high selectivity to increase aromatic and aliphatic hydrocarbons in coal oil.
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I. Fitriana, A. Anindhita, A. Sugiyono, L. M. A. Wahid, and A. Adiarso, Indonesia Energy Outlook 2017: Clean Energy Technology Development Initiatives. Jakarta: Center for Technology of Energy Resources and Chemical Industry BPPT, 2017.
I. Pratiwi, “ESDM: Cadangan Batu Bara Masih 56 Tahun,” Republika Online, Jakarta, 21-Mar-2018.
S. Fan, L.-H. Xu, T.-J. Kang, and H.-T. Kim, “Application of eggshell as catalyst for low rank coal gasification: Experimental and kinetic studies,” J. Energy Inst., vol. 90, no. 5, pp. 696–703, Oct. 2017.
Z. Chen et al., “High quality syngas production from catalytic coal gasification using disposable Ca(OH)2 catalyst,” Chem. Eng. J., vol. 316, pp. 842–849, May 2017.
Warsita, A. “Effective Use of Catalysts and Water Additions to the Removal of the Gasification Tar Biomass Model with a Microwave Reactor.” Mechanical Eng. J., pp 769 - 779, 2017.
D. Sutton, B. Kelleher, A. Doyle, and J. R. H. Ross, “Investigation of nickel supported catalysts for the upgrading of brown peat derived gasification products,” Bioresour. Technol., vol. 80, no. 2, pp. 111–116, Nov. 2001.
N. F. Othman and M. H. Bosrooh, “Catalytic Adaro Coal Gasification Using Dolomite and Nickel as Catalysts,” Procedia Eng., vol. 148, pp. 308–313, Jan. 2016.
J. N. Kuhn, Z. Zhao, L. G. Felix, R. B. Slimane, C. W. Choi, and U. S. Ozkan, “Olivine catalysts for methane- and tar-steam reforming,” Appl. Catal. B Environ., vol. 81, no. 1–2, pp. 14–26, May 2008.
A. C.-C. Chang, L.-S. Chang, C.-Y. Tsai, and Y.-C. Chan, “Steam reforming of gasification-derived tar for syngas production,” Int. J. Hydrogen Energy, vol. 39, no. 33, pp. 19376–19381, Nov. 2014.
A. M. Ribeiro, J. C. Santos, and A. E. Rodrigues, “PSA design for stoichiometric adjustment of bio-syngas for methanol production and co-capture of carbon dioxide,” Chem. Eng. J., vol. 163, no. 3, pp. 355–363, Oct. 2010.
M. Asadullah, T. Miyazawa, S. Ito, K. Kunimori, and K. Tomishige, “Catalyst development for low temperature gasification of biomass: Function of char removal in fluidized bed reactor,” Stud. Surf. Sci. Catal., vol. 145, pp. 307–310, Jan. 2003.
M. Asadullah, T. Miyazawa, S. Ito, K. Kunimori, S. Koyama, and K. Tomishige, “A comparison of Rh/CeO2/SiO2 catalysts with steam reforming catalysts, dolomite and inert materials as bed materials in low throughput fluidized bed gasification systems,” Biomass and Bioenergy, vol. 26, no. 3, pp. 269–279, Mar. 2004.
D. Tristantini, R.K. Suwignjo, “Optimum Temperature and Steam Ratio in the Process of K2NO3 Catalyst Steamed Gasification of Lignite Coal Charcoal from Pyrolysis Results with Controlled Heating Rate.” J. Process Integr. vol 5, no 3, pp. 142 - 149, 2015.
S. Sunarno, R.Y. Silvia, S. Bahri, “The Effect of Temperature and Concentration of Catalysts on Cracking Palm Shells into Bio-Fuel.” Chem. Res. J., vol 5, no 1, pp. 73 - 77, 2011.
F. Yan, S. Luo, Z. Hu, B. Xiao, and G. Cheng, “Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: Influence of temperature and steam on hydrogen yield and syngas composition,” Bioresour. Technol., vol. 101, no. 14, pp. 5633–5637, Jul. 2010.
R. T. Vang et al., “Controlling the catalytic bond-breaking selectivity of Ni surfaces by step blocking,” Nat. Mater., vol. 4, no. 2, pp. 160–162, Feb. 2005.
E. Heraldy, S.W. Hisyam, and S. Sulistiyono, “Characterization and Activation Of Natural Zeolit From Ponorogo,” Indones. J. Chem., vol. 3, no. 2, pp. 91–97, 2003.
Indra, Y.S. “Preparation and Characterization of Ni-Mo / ZAA Catalysts for Catalytic Cracking Processes of Palm Oil Empty Bunches into Liquid Fuels.” Pekanbaru: Chemical Engineering Department, Faculty of Engineering, Riau University, 2010.
S.D.S. Murti, H. Hartiniati, “Catalytic Upgrading of South Banko Coal Oil Distillate with NiMO Sulfide Catalyst.” J. Energy Environ., vol 4, no 2, pp. 48 - 50, 2008.
D.J. Sugianto, K. Wijaya, I. Tahir, “Characterization and Application of Impregnated Nickel-Molybdenum Catalysts on Active Natural Zeolites for Hydrocracking of Coal Tar.” Indones. Nat. J., vol 16, no 1, pp. 10-22, 2014.
L. Muis, H. Anwar, M. Haviz, ”Effect of Temperature on the Process of Anthracite Coal Liquefaction Using Short Residue Solvents.” J. Civronlit Batangharai Univ., vol 3 , no 2, pp. 73 - 81, 2018.
J. Fratczak, J.M.H. Herrador, J. Lederer, L. Stevens, C. Uguna, C. Snape, C. et al., “Direct Primary Brown Coal Liquefaction via Non-Catalytic and Catalytic Co-Processing with Model, Waste and Petroleum-Derived Hydrogen Donors.” Fuel, vol 234, pp. 364 - 370, Dec. 2018.
DOI: http://dx.doi.org/10.24845/ijfac.v4.i2.59
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