Color And COD Degradation of Procion Red Synthetic Dye by Using Fenton-TiO2 Method

Dedi Teguh, Tuty Emilia Agustina, Muhammad Faizal

Abstract


Nowadays, environmental pollution caused by industrial wastewater is quite apprehensive. Most of textile industries used synthetic dyes. Procion red is one of the synthetic dyes that often used in textile industries and classified as a reactive dye that is difficult to decompose in nature and contain harmful toxins. One of the colored wastewater treatment process is by using Fenton reagent and TiO2 catalyst (Fenton-TiO2) as one of Advanced Oxidation Processes (AOPs). The objective of this research is to treat of procion red synthetic dye by using Fenton-TiO2 method and study the effect of procion red concentration, reaction time and the concentrations of TiO2 catalyst on color and COD degradation. In this experiment, the concentrations of procion red were varied between 150-300 ppm, the concentrations of TiO2 catalyst were varied from 0.05 to 0.4% (w/v) and the reaction time of 5 to 20 minutes. The optimum condition was achieved by using procion red concentration of 150 ppm with TiO2 catalyst concentration of 0.4% and reaction time of 20 minutes, which the maximum color and COD degradation of 98.67% and 92% were achieved respectively. This condition was applied to the real wastewater of textile home industry in Palembang. The color and COD degradation of 59% and 44% were found respectively after 220 minutes of reaction.


Full Text:

Full Text PDF

References


S. Dey, and A. Islam, ”A review on textile wastewater characterization in bangladesh, resources and environment,” vol. 5 (1), pp. 15-44, doi:10.5923/j.re.20150501.03, 2015.

M. O. Awaleh, and Y. D. Soubaneh, “Waste water treatment in chemical industries: the concept and current technologies, ”hydrol current res, 5:1 http://dx.doi.org/10.4172/2157-7587.1000164, ISSN: 2157-7587 HYCR, vol. 5, 2014.

F. Balotrawala, ”The classification of synthetic dyes, ”Proprietor at IM Dye Chem, Danilimda, Ahmedabad – 380022, India, 2010.

M. I. Sari, T. E. Agustina, E. Melwita, and T. Aprianti, ”Color and COD degradation in photocatalytic process of procion red by using TiO2 catalyst under solar irradiation, ”AIP Conf. Proc, 1903, 040017-1–040017, https://doi.org/ https://doi.org/10.106 3/1.5011536, 2017.

Y. Deng, and R. Zhao, ”Advanced oxidation processes (AOPS) in wastewater treatment,” Curr Pollution Rep, 1:167–176, DOI 10.1007/s40726-015-0015-z, 2015.

N. Wang, T. Zheng, G. Zhang, and P. Wang, ”A review on Fenton-like processes for organic wastewater treatment, ”Journal of Environmental Chemical Engineering, http://dx.doi.org/10.1016/j.jece.2015.12.016, 4, 762–787, 2016.

S. A. Amiri, J. R. Bolton, and S. R. Cater, ”The use of iron in advanced oxidation processes, ”journal of advanced oxidation technology, vol. 1, pp. 18-26, 1996.

S. Kommineni, J. Zoeckler, A. Stocking, P. S. Liang, A. Flores, R. Rodriguez, T. Brown, R. Per, and A. Brown, ”3.0 Advanced oxidation processes, “ center for groundwater restoration and protection national water research institute, 2000.

A. Tabai, O. Bechiri, and M. Abbessi, “Degradation of organic dye using a new homogeneous Fenton-like system based on hydrogen peroxide and a recyclable Dawson-type

Heteropolyanion, ”Int J Ind Chem, 8:83–89, DOI 10.1007/s40090-016-0104-x, 2017.

W. Teoh, Y, Scott, J. A, and R. Amal, ”Progress in heterogeneous photocatalysis: from classical radical chemistry to engineering nanomaterials and solar reactors, ”J. Phys. Chem. Lett. 3, 629−639, 2012.

A. Rigaa, K. Soutsas, K. Ntampegliotis, V. Karayannis, and G. Papapolymeroua, ”Effect of system parameters and of inorganic salts on the decolorization and degradation of procion H-exl dyes. Comparison of H2O2/UV, Fenton, UV/Fenton, TiO2/UV and TiO2/UV/H2O2 processes, ”Desalination, doi:10.1016/j.desal. 200604.082211,72–86, 2007.

S. A. A. Farha, ”Comparative study of oxidation of some azo dyes by different advanced oxidation processes: Fenton, Fenton-like, photo-Fenton and photo-Fenton-like, ”Journal of American Science, 6(10), 2010.

K. Barbusiński, ”Fenton reaction - controversy concerning the chemistry, ”Ecological Chemistry and Engineerings, Institute of Water and Wastewater Engineering,” Silesian University of Technology, ul. Konarskiego 18, 44-100 Gliwice, vol. 16 (3), Poland, 2009.

R. Munter, ”Advanced oxidation process – current status and prospects, “Proc. Estonian Acad. Sci. Chem, vol. 50, (2), 59-80, 2001.

A.D. Bokare, and W. Choi, “Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes, ”J Hazard.Mat, 275,121-35, 2014.

A. L. Manoj, S. Varghese, and S. S. Nair, ” Photocatalytic water treatment by titanium dioxide: recent updates, ”Catalysts, ISSN 2073-43442, 572-601; doi:10.3390/catal2040572, 2012.

T. E. Agustina, and H. M Ang, ”Decolorization and mineralization of C.I. reactive blue 4 and C.I. reactive red 2 by Fenton oxidation process,” International Journal of Chemical and Environmental Engineering, 3, 142-147, 2012.

T. E. Agustina, Y. Wijaya, and F. Mermaliandi, ”Degradation of reactive red 2 by Fenton and photo-Fenton oxidation processes, ”ARPN Journal of Engineering and Applied Sciences, ISSN 1819-6608, vol. 11 (8), 2016.




DOI: http://dx.doi.org/10.24845/ijfac.v3.i1.23

Refbacks

  • There are currently no refbacks.


 

Editorial Office:

Jurusan Kimia, Fakultas MIPA Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.32
Indralaya 30662
Phone: +62-711-580269

 

Creative Commons License
IJFAC by Department of Chemistry Sriwijaya University is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License