Fixed-Bed Column for the Removal of Cd(II) from Aqueous by Hydroxyapatite from Red Snapper (Lutjanus campechanus) Fish Bone

Widia Purwaningrum, Fahma Riyanti, Muhammad Said, Poedji Loekitowati Hariani, Aria Septi Handayani

Abstract


The Synthesis of hydroxyapatite from Red Snapper (Lutjanus campechanus) fish bone carried out. Hydroxyapatite is utilized for Cd(II) sorption from solution using a fixed-bed column. Hydroxyapatite was characterized using X-ray Diffraction, Fourier Transform Infra-Red, Scanning Electron Microscope-Electron Dispersive, and Thermogravimetric. In fixed-bed column, the influence of bed height (5, 10, 15 cm) and flow rate (6, 8 and 10 mL/min) were studied. The highest adsorption capacity is obtained at a bed height of 15 cm, and a flow rate of 6 mL/min with adsorption capacity is 47.027 mg/g. The predicted by Bed Depth Service Time (BDST) model obtained that value of R2 in the range 0.9964-0.9997. The adsorption capacity per unit volume ( is in the range 141.12-222.89 mg/L while  is in the range 0.0136-0.022 L/mg h. This indicates that BDST can be used to explain the performance of Cd(II) sorption onto hydroxyapatite by fix-bed column.


Full Text:

Full Text - PDF

References


R.A.K Rao and M. Kashifuddin. “Adsorption studies of Cd(II) on ball clay: comparison with other natural clays.” Arabian Journal of Chemistry, vol. 9, No. 2, pp. S1233–S1241, 2016.

H. Javadian, F. Ghorbani, H. Tayebi, S.H. Asl, “ Study of the adsorption of Cd (II) from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies.” Arabian Journal of Chemistry, vol. 8, pp. 837–849, 2015.

E. Elkhatib, A. Mahdy, F. Sherif, W. Elshemy. “Competitive adsorption of cadmium (ii) from aqueous solutions onto nanoparticles of water treatment residual.” Journal of Nanomaterials, vol. 2016, pp. 1–10, 2016.

Q. Peng, L. Liu, Y. Luo, Y., Zhang, W. Tan, F. Liu, F.L. Suib, G. Qiu. “Cadmium removal from aqueous solution by deionization supercapacitor with birnessite electrode.” ACS Applied Materials & Interfaces, vol. 8, no. 50, pp. 34405–34413, 2016.

D. Mohan, K.P. Singh, V.K. Singh. “Trivalent chromium removal from wastewater using low cost activated carbon fabric cloth.” Journal of Hazardous Materials, vol. 153, pp. 280–295, 2006.

O.S. Amuda, I.A. Amoo, K.O. Ipinmoroti, O.O., Ajayi. “Coagulation/flocculation process in the removal of trace metals present in industrial wastewater.” Journal of Applied Sciences and Environmental Management, vol. 10, no. 3, pp. 159–162, 2006.

Y. Bai, B. Bartkiewicz. “Removal of cadmium from wastewater using ion exchange resin amberjet 1200H columns.” Polish Journal of Environmental Studies, vol. 18, no. 6, pp. 1191–1195, 2009.

D.J. Ennigrou, L. Gzara, M.R.B. Romdhane, M. Dhahbi. “ Cadmium removal from aqueous solutions by polyelectrolyte enhance ultrafiltration.” Desalination, vol. 246 (1-3), pp. 42–48, 2009.

M. Byambaa, E. Dologor, K. Shiomori, Y. Suzuki. “Removal and recovery of heavy metals from industrial wastewater by precipitation and foam separation using lime and casein.” Journal of Environmental Science and Technology, vol. 11, No. 1, pp. 1–9, 2018.

Z. Xue, N. Liu, H. Hu, J. Huang, Y.K. Kalkhajaeh, X. Wu, N. Xu, X. Fu, L. Zhan. “Adsorption of Cd(II) in water by mesoporous ceramic functional nanomaterials.” Royal Society Open Science, vol. 6, pp. 1–11, 2019.

E. Oguz. “Fixed-bed column on the removal of Fe3+ and neural network modelling. Arabian Journal of Chemistry.” vol. 10, pp. 313–320, 2017.

N.A.S.M. Pu’ad, P. Koshy, H. Z. Abdullah, M.I. Idris, T.C. Lee. ”Syntheses of hydroxyapatite from natural sources.” Heliyon, vol. 5, No. 5, pp. 1–14, 2019

E. Skwarek, A.G. Palaska, J.B. Choromanska, E. Broda. “Adsorption of uranium ions on nano-hydroxyapatite and modified by Ca and Ag ions,” Adsorption, vol. 25, pp.639–647, 2019.

A.R. Ibrahim, Y. Zhou, X. Li, L. Chen, Y. Hong, Y. Su, H. Wang, J. Li. “Synthesis of rod like hydroxyapatite with high surface area and pore volume from eggshell for effective adsorption of aqueous Pb(II).” Materials Research Bulletin, vol. 62, pp. 132–141, 2015.

M. Mourabet, A.El. Rhilassi, H. El. Boujaady, M.B. Ziatni, R.El. Hamri, A. Taitai. “Removal of fluoride from aqueous solution by adsorption on hydroxyapatite (Hap) using response surface methodology.” Journal of Saudi Chemical Society, vol. 19, No. 6, pp. 603–615, 2015.

B.R. Sunil, and M. Jaganathan. “Producing hydroxyapatite from fish bone by heat treatment.” Materials Letters, vol. 185, pp. 411–414, 2016.

M. Boutinguinza, J. Pou, R. Comesana, F. Lusquinos, A. Carlos, B. Leon, “Biological hydroxyapatite obtained from fish bones”, Materials Science and Engineering: C, 32, 478–486, 2012.

A. Kara, G.E. Ustun, S.K.A. Solmaz, E. Demirbel. “Removal of Pb(II) ions in fixed-bed column from electroplating wastewater of Bursa, an industrial city in Turkey.” Journal of Chemistry, vol. 2013, pp.1–6, 2013.

S. Srivastava, S.B. Agrawal, M.K. Mondal. “Fixed bed column adsorption Cr(VI) from aqueous solution using nanosorbents derived from magnetite impregnated Phaseolus vulgaris Husk.” Environmental Progress & Sustainable Energy, vol. 2018, pp. 1–9, 2018.

P.L. Hariani, and M. Said, Salni. “Effect sintering on the mechanical properties of hydroxyapatite from fish bone (Pangasius Hypohtalmus).” in IOP Conference Series: Materials Science and Engineering., 509, 1–9, 2019.

M. Mujahid, S. Sarfraz, S. Amin. “On the formation of hydroxyapatite nano crystals prepared using cationic surfactant”, Materials Research, vol. 18, No. 3, pp. 468–472, 2015.

V.R. Lugo, T.V.K. Karthik, D.M. Anaya, E.R. Rosas, L.S.V. Ceron, M.I.R. Valderrama, E.S. Rodriguez. “Wet chemical synthesis of nanocrystalline hydroxyapatite falkes: effect of pH and sintering temperature on structural and morphological properties.” Royal Society Open Science, vol. 5, pp. 1–14., 2018.

M. Manoj, D. Mangalaraj, N. Ponpandian, C. Viswanathan. “Core shell hydroxyapatite/Mg nanostructure: surfactant free facile synthesis, characterization and their in-vitro cell viability studies against leukemia cancer cells (K562).” RSC Advances, vol. 5, pp. 48705–48711. 2015.

J. Venkatesan, B. Lowe, P. Manivasagan, K. Kang, E.P. Chalisserry, S. Anil, DG. Kim, S. Kim. “Isolation and characterization of nano-hydroxyapatite from salmon fish bone.” Materials, vol. 8, pp. 5426–5439, 2015.

C. Yunnen, W. Ye, L. Chen, G. Lin, N. Jinxia, R. Rushan. “Continuous fixed-bed column study and adsorption modeling: removal of arsenate and arsenite in aqueous solution by organic modified spent grains.” Polish Journal of Environmental Studies, vol. 26, No. 4, pp. 1847–1854, 2017.

I. Mobasherpour, E. Salahi, M. Pazouki. “Comparative of the removal of Pb2+, Cd2+ and Ni2+ by nano crystallite hydroxyapatite from aqueous solutions: adsorption isotherm study.” Arabian Journal of Chemistry, vol. 5, pp. 439–446, 2012.


Refbacks

  • There are currently no refbacks.


 

Editorial Office:

Department of Chemistry, Faculty of Mathematics and Natural Sciences Universitas Sriwijaya
Jl. Palembang-Prabumulih Km.32 Indralaya 30662
Phone: +62-711-580269

 

Creative Commons License
IJFAC by Department of Chemistry Sriwijaya University is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License